catena-Poly[[aqua(1,10-phenanthroline)cobalt(II)]-μ-4,4′-(propane-1,3-diyldioxy)dibenzoato]
نویسنده
چکیده
In the title compound, [Co(C(17)H(14)O(6))(C(12)H(8)N(2))(H(2)O)](n), the Co(II) atom is coordinated by a monodentate 4,4'-(propane-1,3-diyldi-oxy)dibenzoate (cpp) dianion, a water mol-ecule and a chelating 1,10-phenanthroline (phen) ligand. A symmetry-generated cpp ligand completes the CoN(2)O(3) trigonal-bipyramidal geometry for the metal ion, with the N atoms occupying both equatorial and axial sites. The bridging cpp ligands form chains propagating in [110] and O-H⋯O hydrogen bonds consolidate the packing.
منابع مشابه
catena-Poly[[(1,10-phenanthroline)cobalt(II)]-di-μ-azido]
In the crystal structure of the binuclear title complex, [Co(N(3))(2)(C(12)H(8)N(2))](n), each Co(II) cation is coordinated by two N atoms from one chelating 1,10-phenanthroline ligand and four azide ligands in a slightly distorted octa-hedral coordination. The two Co(II) cations of the binuclear complex are related by an inversion centre and are bridged by two symmetry-related azide ligands in...
متن کاملcatena-Poly[[[aqua(1,10-phenanthroline-κ2 N,N′)manganese(II)]-{μ-4,4′-[(4-carboxybenzyl)nitrilo]dibenzoato-κ4 O,O′:O′′,O′′′}] monohydrate]
The title compound, {[Mn(C(22)H(15)NO(6))(C(12)H(8)N(2))(H(2)O]·H(2)O}(n), was obtained under solvothermal conditions. The Mn(2+) cation exhibits a distorted penta-gonal-bipyramidal MnN(2)O(5) coordination sphere with the water O atom and one of the phenanthroline N atoms in the axial positions. The cation is bridged by the doubly deprotonated 4,4'-[(4-carb--oxy-benz-yl)nitrilo]-dibenzoate liga...
متن کاملcatena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)cadium(II)]-μ-4,4′-ethylenedibenzoato] N,N-dimethylformamide hemisolvate]
In the title compound, [Cd(C(16)H(10)O(4))(C(14)H(8)N(4))(H(2)O)]·0.5C(3)H(7)NO, the Cd(II) atom is six-coordinated by two N atoms from one pyrazino[2,3-f][1,10]phenanthroline ligand, three carboxyl-ate O atoms from two different 4,4'-ethyl-enedibenzoate ligands, and one water mol-ecule in a distorted octa-hedral environment. The two 4,4'-ethyl-enedibenzoate dianions are located on inversion ce...
متن کاملCrystal structure of bis{μ-4,4′-[1,3-phenylenebis(oxy)]dibenzoato-κ4 O,O′:O′′,O′′′}bis[(1,10-phenanthroline-κ2 N,N′)zinc(II)] dihydrate
Two 4,4'-[1,3-phenyl-enebis(-oxy)]dibenzoate anions bridge two 1,10-phenanthroline-chelated Zn(II) cations about a center of inversion to generate the dinuclear title compound, [Zn2(C20H12O6)2(C12H8N2)2]·2H2O. The geometry about the Zn(II) atom is a distorted octa-hedron. In the crystal, the mol-ecules are connected by classical O-H⋯O hydrogen bonds, weak C-H⋯O hydrogen bonds and C-H⋯π inter-ac...
متن کاملcatena-Poly[[[aqua(1,10-phenanthroline)manganese(II)]-μ-adamantane-1,3-dicarboxylato] monohydrate]
In the title coordination polymer, {[Mn(C(12)H(14)O(4))(C(12)H(8)N(2))(H(2)O)]·H(2)O}(n), the Mn(II) atom has a highly distorted cis-MnN(2)O(4) octa-hedral geometry arising from its coordination by a bidentate phenanthroline ligand, a water mol-ecule and monodentate and bidentate adamantane-1,3-dicarboxyl-ate dianions. The bridging dianion leads to [001] chains in the crystal. The chains are li...
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